✦ LIBER ✦

Spectral Tuning of Azobenzene Photoswitches for Biological Applications

✍ Scribed by Oleg Sadovski; Andrew A. Beharry; Fuzhong Zhang; G. Andrew Woolley

Publisher: John Wiley and Sons
Year: 2009
Tongue: English
Weight: 344 KB
Volume: 121
Category: Article
ISSN: 0044-8249
DOI: 10.1002/ange.200805013

No coin nor oath required. For personal study only.

✦ Synopsis

Abstract

Längere Schaltwellenlängen und gute photochemische Ausbeuten und Stabilitäten des cis‐Isomers in reduzierenden wässrigen Umgebungen kennzeichnen 4,4′‐Diamido‐substituierte Azobenzole mit 2,2′‐Aminoalkyl‐Substituenten. Die Produkte eignen sich zur Photosteuerung biomolekularer Strukturen in zellulären Umgebungen, etwa zum Umschalten zwischen zwei Peptidkonfigurationen (siehe Bild).magnified image

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