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Spectral theory of molecular rotation-induced broadening of hyper-Raman lines in liquids

✍ Scribed by W. Alexiewicz; T. Bancewicz; S. Kielich; Z. Ożgo

Publisher
John Wiley and Sons
Year
1974
Tongue
English
Weight
504 KB
Volume
2
Category
Article
ISSN
0377-0486

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Vibrational phase and energy relaxation
Vibrational phase and energy relaxation in the broadening of Raman spectral lines in dense media
✍ D.J. Diestler 📂 Article 📅 1976 🏛 Elsevier Science 🌐 English ⚖ 574 KB

An explicit quantum-mechanical expression for the linewidth of the isotropic Raman band for a dilute solution of Raman-active molecules in an "inert" solvent is summa&y derived. Line broadeh in such a system vises from two mechanisms: pure vibrariond dephasing, which is due to nearly elastic scatter