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Spectral properties and kinetics of cationic transients generated in electron-pulse-irradiated alkanes

✍ Scribed by R. Mehnert; O. Brede; W. Naumann

Publisher
Elsevier Science
Year
1985
Weight
373 KB
Volume
26
Category
Article
ISSN
0146-5724

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The transient absorption bands dm 3 9 Οͺ1 ( Ο­ 330, 525 nm, k Ο­ 5 Ο« 10 mol max f obtained on pulse radiolysis of N 2 O-saturated neutral aqueous solution of 4,4Ј-thiodi-Οͺ1 s ) phenol (TDPH) are due to the reaction of TDPH with ΠΈOH radicals and are assigned to phenoxyl radical formed on fast deprotonat