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Spectral, Kinetics, and Theoretical Studies of Radical Cations Derived from Thioanisole and Its Carboxylic Derivative

✍ Scribed by Korzeniowska-Sobczuk, Anna; Hug, Gordon L.; Carmichael, Ian; Bobrowski, Krzysztof

Book ID
120244458
Publisher
American Chemical Society
Year
2002
Tongue
English
Weight
183 KB
Volume
106
Category
Article
ISSN
1089-5639

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Using aqueous TiCI,-based continuous-flow, radical-generating methods, a comprehensive investigation was made of radicals derived from fumaronitrile and cis-and trans-carboxylic acids of general structure CY(COOH)=CH(COOH), where Y is H, CH, or CH,COOH. All substrates were examined at 25Β°C but, wher