Spectral investigation of the hydrogen bonds of tert-butyl alcohol and phenol with some electron-donor solvents
✍ Scribed by B. V. Rassadin; A. V. Iogansen; V. A. Marchenko; F. S. Yakushin; A. I. Shatenshtein
- Publisher
- Springer US
- Year
- 1972
- Tongue
- English
- Weight
- 380 KB
- Volume
- 17
- Category
- Article
- ISSN
- 0021-9037
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## Abstract Four bicyclic dioxetanes bearing a phenolic substituent, 3‐__tert__‐butyldimethylsiloxy‐4‐chlorophenyl (**3a**), 5‐__tert__‐butyldimethylsiloxy‐4‐chloro‐2‐ethylphenyl (**3b**), 5‐__tert__‐butyldimethylsiloxy‐2‐ethylphenyl (**3c**), and 3‐__tert__‐butyldimethylsiloxy‐4‐ethylphenyl (**3d*
A systematic PCILO study has been carried out on the intermolecular hydrogen bond formed by phenol with proton acceptors such as acetone, ether, p-benzoquinone, N,N-dimethylfonnamide, trimethylamine, pyridine, acetonitrile and acrylonitrile. The complexes studied form hydrogen bonds with energy inte