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Spectral hole-burning isolation of fluorescent species in jet-cooled 9-methoxyanthracene complexes with water and alcohols

✍ Scribed by F. Lahmani; J. Sepiol


Publisher
Elsevier Science
Year
1992
Tongue
English
Weight
570 KB
Volume
189
Category
Article
ISSN
0009-2614

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✦ Synopsis


The fluorescent complexes of 9-methoxyanthracene with protic solvents generated in a supersonic expansion have been investigated by means of the pump and probe hole-burning technique. These spectra allow to discriminate between different geometrical isomers and clusters and to give details on their low frequency vibrational pattern. In the case of 9-methoxyanthracene: methanol complexes, two different 1: 1 isomers corresponding to different sites of interactions have been evidenced.