Spectral Evidence for Single Electron Transfer in Nucleophilic Aliphatic Substitution of a Carbanion by Methyl Iodide

Nucleophilic Substitution Reaction of p

Nucleophilic Substitution Reaction of p -Dinitrobenzene by a Carbanion: Evidence for Electron Transfer Mechanism

✍ You-Cheng Liu; Kai-Dong Zhang; Jian-Ming Liu; Long-Min Wu; Zhong-Li Liu 📂 Article 📅 2010 🏛 John Wiley and Sons 🌐 English ⚖ 256 KB 👁 1 views

A Photochemical Probe for Single Electro

A Photochemical Probe for Single Electron Transfer in Nucleophilic Aliphatic Substitution: Evidence for Geminate Radical Coupling in the Solvent Cage

✍ Tolbert, Laren M.; Sun, Xiao-Jing; Ashby, E. C. 📂 Article 📅 1995 🏛 American Chemical Society 🌐 English ⚖ 572 KB

Another challenge to the validity of the

Another challenge to the validity of the use of cyclizable probes as evidence for single-electron transfer in nucleophilic aliphatic substitution. The reaction of lithium aluminum hydride with alkyl iodides

✍ Ashby, E. C.; Pham, Tung; Madjdabadi, A. Amrollah 📂 Article 📅 1988 🏛 American Chemical Society 🌐 English ⚖ 389 KB

Evidence for single electron transfer in

Evidence for single electron transfer in the reaction of a lithium enolate with a primary alkyl iodide

✍ E.C. Ashby; J.N. Argyropoulos 📂 Article 📅 1984 🏛 Elsevier Science 🌐 French ⚖ 205 KB

Evidence for a radical process in the reaction of the lithium enolate of propiophenone with a primary alkyl iodide was obtained by the observation of cyclization of an appropriate radical probe, by the trapping of the radical intermediate and by the comparison of the relative rates of reactions of t

Does the Nucleophilic Substitution of Ha

Does the Nucleophilic Substitution of Halogen in o- and p-Halonitrobenzenes with Cyanoacetate Carbanions Proceed via Single Electron Transfer and a Nonchain Radical Process?

✍ Makosza, Mieczyslaw; Podraza, Renata; Kwast, Andrzej 📂 Article 📅 1994 🏛 American Chemical Society 🌐 English ⚖ 477 KB

Another challenge to the validity of the

Another challenge to the validity of the use of cyclizable probes as evidence for single-electron transfer in nucleophilic aliphatic substitution. The reaction of lithium aluminum hydride with alkyl iodides [Erratum to document cited in CA110(3):23019s]

✍ Ashby, E. C.; Pham Tung, ; Madjdabadi, A. Amrollah 📂 Article 📅 1989 🏛 American Chemical Society 🌐 English ⚖ 78 KB