Kinetic studies on the oxidative degradation of phenol, o-chlorophenol and catechol present in dilute aqueous solutions in the concentration range between 50 ppm and 1000 ppm by hydrogen peroxide were conducted in a batch reactor. The temperature was varied between 298 K and 333 K. Initial rates of
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Spectral and kinetic studies on the interaction between oxyhaemoglobin and peroxynitrite: a comparison with hydrogen peroxide
โ Scribed by Rui-yong Wang; Mi-na Ji; Ru-xiu Cai; Ying-tang Lu
- Publisher
- John Wiley and Sons
- Year
- 2005
- Tongue
- English
- Weight
- 412 KB
- Volume
- 20
- Category
- Article
- ISSN
- 1522-7235
- DOI
- 10.1002/bio.842
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High-valent oxo-iron(IV) species are commonly proposed as the key intermediates in the catalytic mechanisms of iron enzymes. Water-soluble iron(III) tetrakis-5,10,15,20-(N-methyl-4-pyridyl)porphyrin (Fe(III)TMPyP) has been used as a model of heme-enzyme to catalyse the hydrogen peroxide (H 2 O 2 ) o