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Spectra and stabilities of α-substituted phthalocyaninatoirons

✍ Scribed by Liang Yang; Mei-Jin Lin; Xiao-Li Zhu; Xiu-Zhi Xu; Jun-Dong Wang

Publisher: Elsevier Science
Year: 2006
Tongue: English
Weight: 292 KB
Volume: 253
Category: Article
ISSN: 1381-1169
DOI: 10.1016/j.molcata.2006.02.069

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✦ Synopsis

Three aryloxy (alkoxy) ␣-substituted phthalocyaninatoirons (FePcs) were prepared and their UV-vis spectra in air or by adding of peroxide showed a new band at the red side of the Q band which can be assigned to a complexes of phthalocyaninatoirons with oxygen or peroxide. The appearance of this band related to the instability of these FePcs so their decomposition was also studied, by the benzoylperoxide oxidation.

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