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Spectra and conformation of α-naphthil

✍ Scribed by Dipankar Sen; Bidyut Kumar Manna; Subhash Ch. Bera

Book ID
107806815
Publisher
Elsevier Science
Year
1992
Tongue
English
Weight
682 KB
Volume
271
Category
Article
ISSN
0022-2860

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Molecular configuration of α-naphthil
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X-ray crystallographic studin on the molecular structure of enaphthil reveal that the intercarbonyl dihedral angle 1s 87\_29O whereas the naphthslene groups make angles of4.260 and 6.9B" with the respective carbanyl planes. The two naphthalene moieties are twisted about their central bonds

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The flash photolysis of o-naphthil was studied in the temperature range 77-320 K. Flash excited a-naphthil produces two triplet conformers and two types of hydrogen-adduct radical in the presence of a hydrogen donor. In isopropanol, one triplet conformer absorbs at 525 nm (triplet I) and the other a

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Energy levels of mesitil, as obtained through absorption, emission and excitation spectra, have been discussed in relation to the conformation of the molecule. A conformational equilibrium in non-polar solvents has been suggested.