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Specific structural assignments for O-acetyl group resonances in the 1H-n.m.r. spectrum of 1,2,3-tri-O-acetyl-4-O-(2,3,4-tri-O-acetyl-β-D-xylopyranosyl)-β-D-xylopyranose

✍ Scribed by Jean-Pierre Utille


Publisher
Elsevier Science
Year
1983
Tongue
English
Weight
145 KB
Volume
121
Category
Article
ISSN
0008-6215

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5-Dcoxy-J,2-O-isopropylidene-S-C-(methoxyphenylphosphinyl)-~-O-~~thyl-n-D-ribofuranose (4) was prepared from 1,2-0-isopropylidene-3-O-methyl-a-D-ribo-pentodialdo-1,4-furanose by an addition reaction with methyl phenylphosphinate, followed by deoxygenation of the terminal HO-$H-P group of the adduct