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✦ LIBER ✦
Specific para-hydroxylation of nitronaphthalenes with cumene hydroperoxide in basic aqueous media
✍ Scribed by Lei Zhu; Lin-hua Zhang
- Book ID
- 104210228
- Publisher
- Elsevier Science
- Year
- 2000
- Tongue
- French
- Weight
- 125 KB
- Volume
- 41
- Category
- Article
- ISSN
- 0040-4039
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✦ Synopsis
A synthetic method for specific para-hydroxylation of nitroarenes has been developed. The reaction of nitronaphthalenes with cumeme hydroperoxide in basic aqueous media produces exclusively para-hydroxy nitronaphthalenes in good yield. The selectivity of ortho and para hydroxylation is mediated by water content. The rationale for water-controlled orientation of hydroxylation has been briefly discussed.
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ChemInform Abstract: Specific para-Hydro
✍
Lei Zhu; Lin-hua Zhang
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Article
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2010
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John Wiley and Sons
⚖ 28 KB