Specific Intermolecular Interactions of Nitrogenated and Bioorganic Compounds

✍ Scribed by Alexei K. Baev (auth.)

• Publisher: Springer-Verlag Berlin Heidelberg
• Year: 2014
• Tongue: English
• Leaves: 603
• Edition: 1
• Category: Library

✦ Synopsis

After his first book on the topic "Specific Intermolecular Interactions of Organic Compounds", Baev extends in this book the development of the thermodynamic theory of specific intermolecular interactions to a wider spectrum of nitrogenated and bioorganic compounds: amino alcohols, amino acids, peptides and urea derivatives. The fundamentals of an unconventional approach to the theory of H-bonding and specific interactions are formulated based on a concept of penta- coordinated carbon atoms. New types of hydrogen bonds and specific interactions are substantiated and on the basis of the developed methodology their energies are determined. The new concept of the extra stabilizing effect of isomeric methyl groups on the structure and stability of nitrogenated organic molecules and bioorganic compounds is introduced and the destabilization action on specific interactions is outlined.

✦ Table of Contents

Front Matter....Pages i-xxvii
Hydrogen Bonds and Specific Intermolecular Interactions of Nitrogenated and Bio-organic Compounds and the Methodology of their Investigation....Pages 1-19
Specific Intermolecular Interactions of Cyclic Alkylamines and Nitriles....Pages 21-88
Specific Intermolecular Interactions of Cyclic Aromatic Compounds with Nitrogen Atom in Their Functional Groups....Pages 89-154
Specific Intermolecular Interactions of Nitrogen Containing Five-Membered Heterocycles....Pages 155-188
Specific Intermolecular Interactions of Nitrogen Containing Six-Membered Heterocycles....Pages 189-260
Specific Intermolecular Interactions of Methoxyamines, Methoxynitriles, and Amides....Pages 261-334
Specific Intermolecular Interactions of Nitrogen and Oxygen Containing Cyclic Hydrocarbons....Pages 335-393
Specific Intermolecular Interactions of Amino Alcohols and Their Derivatives....Pages 395-434
Specific Intermolecular Interactions and Energies of Amino Acids and Esters....Pages 435-495
Specific Intermolecular Interactions and Energies of Compounds with Peptidic Structure....Pages 497-538
Specific Intermolecular Interactions of Urea, Uracile, and Their Derivatives....Pages 539-573
Back Matter....Pages 575-579

✦ Subjects

Theoretical and Computational Chemistry; Bioorganic Chemistry; Physical Chemistry