A sample of nominal BiLsoPbo.43SrL71Ca2a4Cu3Om+x (Bi-2223) composition consisting primarily of fine grains of Bi2Sr2CaCu2Os+x (Bi-2212 ) and CazPbO4 was synthesized under pure oxygen by a solid-state reaction. This assemblage was then convened to large grains of the 110 K superconducting Bi-2223 pha
Specific heat of a multiphase superconductor Bi1.71Pb0.43Sr1.71Ca2.14Cu3O10.29
โ Scribed by M.K. Yu; J.P. Franck; S. Gygax
- Publisher
- Elsevier Science
- Year
- 1990
- Tongue
- English
- Weight
- 351 KB
- Volume
- 165-166
- Category
- Article
- ISSN
- 0921-4526
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โฆ Synopsis
We report on specific heat measurements in the range 2.7 to 25 K and 50 to 120 K on the high T c superconductor Bi l.7IPb0.43SrI.71 Ca2.l4Cu301O.29' The sample contains approximately 70% 2223 phase and 30% 2212 phase, with transition temperatures near] 08.9 and 82 K. Small discontinuities in CIif of 37 mJ/moleK2 (2223 phase) and 11 mJ/mole K2 (2212 phase) are observed. Fitting of the data in the range 2.7 to 8 K to the function C p = A/T 3 + BIT5 + if + aT3 + ~T5 leads to a vanishing y. Representing the lattice term by a sum of atomic Debye functions, one finds that a second anomaly exists in the range 5 to 30 K. It is not of lattice origin, but either a Schottky or spin glass anomaly. The anomaly has a maximum of 1.8 J/mole K at a temperature of ] 7 K.
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