The gas-phase clustering reactions of SF~, SF 6 and F-ions with SF 6 were measured using a high-pressure mass spectrometer. The bond energies of SFs--(SF6) 1 and SF6(SF6) 1 were estimated to be ~< 2.3 kcal/mol. The bond energies of F-(SF6) , with n = 1 and 2 were determined to be 5.4 and = 4.1 kcal/
Specific deactivation of the four 1s states of argon by N2 and SF6
✍ Scribed by J. Le Calvé; R.A. Gutcheck; O. Dutuit
- Publisher
- Elsevier Science
- Year
- 1977
- Tongue
- English
- Weight
- 510 KB
- Volume
- 47
- Category
- Article
- ISSN
- 0009-2614
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✦ Synopsis
By means of pulsed electron beam ercicacio# and kinetic absorptbn spectroscopy, fate coefficients for quenchirzg the Ar 3Po,l.2 and ~PI states by SF, and JVz were found to nnge from 2.6 to 10 X IO"' cmB/s, and 1.4 to 5.7 X IO-" cm3/s, respcetirely. For the N2 measurements, femilry miWm% of Ar/SF6/1)12 permitted US to study the role played by low ene&y electrons during the after_elow.
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