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Specific Behavior of the Propagating Macromolecules in Bis(π-crotylnickel iodide)-Catalyzed Polymerization of Butadiene

✍ Scribed by Churlyaeva, L. A.; Valuev, V. I.; Dmitrieva, T. S.; Lobach, M. I.; Sokolov, V. N.; Shlyachter, R. A.; Kormer, V. A.

Book ID: 126959519
Publisher: American Chemical Society
Year: 1976
Tongue: English
Weight: 432 KB
Volume: 9
Category: Article
ISSN: 0024-9297
DOI: 10.1021/ma60050a006

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Investigation of the individual stages of 2-alkylbutadiene polymerization with bis-(π-crotylnickel iodide)—II: Propagation reactions

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A kinetic study has been made of the polymerizations of isoprene, 2-ethyl-and 2-isopropylbutadienes initiated by bis-(n-crotylnickel iodide). The calculated rate constants of the poly-2-alkylbutadiene chain propagation were correlated with those of anti-syn isomerization of the g-allylic active site