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Specific and stereospecific water eliminations in the mass spectra of bicyclo[3.3.1]nonanols

✍ Scribed by J. Cable; J. K. MacLeod; M. R. Vegar; R. J. Wells


Publisher
John Wiley and Sons
Year
1973
Tongue
English
Weight
728 KB
Volume
7
Category
Article
ISSN
1076-5174

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## Abstract Specific deuterium labelling revealed that podocarpan‐12α‐ and ‐14α‐01, representing conformationally well defined cyclohexanols, eliminate water mainly by stereospecific 1,3 reactions involving __cis__ tertiary hydrogens on electron‐impact. Dehydration of podocarpan‐12ΓŸβ€0l, which also