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Special features of ethylene epoxidation by peroxyacetic acid

✍ Scribed by N. B. Filimonova; A. V. Vorob’ev; K. V. Bozhenko; N. I. Moiseeva; S. P. Dolin; A. E. Gekhman; I. I. Moiseev

Book ID
111472676
Publisher
Pleiades Publishing
Year
2010
Tongue
English
Weight
294 KB
Volume
4
Category
Article
ISSN
1990-7931

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Oxidation of saturated hydrocarbons with
Oxidation of saturated hydrocarbons with peroxyacetic acid catalyzed by vanadium complexes
✍ Laura Gonzalez Cuervo; Yuriy N. Kozlov; Georg Süss-Fink; Georgiy B. Shul’pin 📂 Article 📅 2004 🏛 Elsevier Science 🌐 English ⚖ 176 KB

Peroxyacetic acid (PAA) oxidizes alkanes in acetonitrile or acetic acid at 60 • C if a soluble vanadium(V) salt, n-Bu 4 NVO 3 (1), is used as a catalyst. Corresponding ketones, alcohols and alkyl hydroperoxides are the main products. Methane, ethane, propane, cyclohexane, and other higher alkanes we