Spatial Requirements of Pyridine N-Oxide Oxygen
✍ Scribed by Prof. Dr. Fritz Vögtle; Helga Risler
- Publisher
- John Wiley and Sons
- Year
- 1972
- Tongue
- English
- Weight
- 206 KB
- Volume
- 11
- Category
- Article
- ISSN
- 0044-8249
No coin nor oath required. For personal study only.
✦ Synopsis
The spatial requirements of the oxygen in pyridine N-oxides have apparently not yet been studied. The polar O t N group, having ca. 40% double bond character according t o recent calculations'21, is particularly interesting because it can exert polarizing effects in different directionsf3'.
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## Abstract magnified image Treatment of pyridine __N__‐oxides with dimethylthiocarbamoyl chloride in boiling acetonitrile effects chemoselective deoxygenation to pyridines.