Preface
Introduction
Chapter 1. Problems of isomorphism and phase-formation
1.1. Theoretical studies of isomorphic replacements
1.2. Basic phase-formation factors
1.3. Some modern theories about phase-formation problems
Chapter 2. Spatial-energy parameter (P-parameter)
2.1. Dependencies between energy, charge and dimensional characteristics inside an atom
2.2. Principle of adding reverse values of energy parameters of oppositely charged systems. P-parameter
2.3. Calculations of total energy of valence electrons inside an atom using SEP method. Comparison with a statistic model
2.4. Calculations of electron density inside an atom via P-parameter and principle of adding reverse values of P-parameters
2.5. Dependence of P-parameter upon the modulus of maximum values of Y-function radial part
2.6. Dependence of spectral characteristics of atoms upon their spatial-energy parameters
2.7. Wave equation of P-parameter
2.8. Wave properties of P-parameter and addition principles of P-parameters
2.9. Some additive properties of P-parameter
2.10. P-parameter as an objective characteristics of electronegativity
Chapter 3. Experimental evidence of spatial-energy criterion of isomorphism and solubility
3.1. Elementary systems of Mβ - Mβ type
3.2. Estimation of isomorphic replacements in complex systems
3.3. Experimental check of P-parameter application taking atom coordination into account
3.4. Morphology of state diagrams of quasi-binary systems of vanadates of metals of II group
3.5. Application of effective PE-parameter
Chapter 4. Temperature characteristics of solid solution expansion with the help of Pparameter (at given temperature)
4.1. Estimation of mutual solubility of binary system components
4.2. Systems of Mβ0 - Mβ0 type
4.3. Phase-formation and thermal properties in systems A12O3-M2O3
4.4. Estimation of carbon solubility in metals for refractory compounds at given temperature
4.5. Calculations of oxygen solubility in metals
4.6. Method experimental check; directed search of inorganic materials
Chapter 5. Spatial-energy criterion of compound formation
5.1. P-parameter as a basic criterion of stable phase formation
5.2. Crystals with basic ionic bond
5.3. Crystals with ionic-covaience and metallic bonds. Intermetallides
5.4. Crystalline penetration structures
5.5. Estimation of ultimate carbon content value in carbide systems MCl-x
Chapter 6. Other applications of P-parameter in inorganic chemistry and chemistry of solids
6.1. Calculations of effective ionization sections of atoms and molecules at electron shock
6.2. Shift modulus determination for metals and carbide compounds
6.3. Calculations of activation energy of volume diffusion and self-diffusion in solids
6.4. Estimation of alloy amorphization possibility
6.5. Solubility of components of solid solutions of system W-Co-C-O-N
6.6. Estimation of cluster-formation in system CaSO4-H2O
Chapter 7. Kinetics and phase-formation in fast physic-chemical processes
7.1. Methods for calculating P-parameters of complex organic compounds
7.2. Dependence of activation energy of chemical reactions upon spatial-energy characteristics of atoms
7.3. Basic structural interactions of components in systems OCTOGEN (OG) β nitroglycerine (NG)
7.4. Phase-formation features of polymeric composite (PC) components
Conclusion
General conclusions
References
Appendix I. P-parameter additive properties
Appendix II. Isomorphism of elementary systems
Appendix III. PO-parameters of valence orbitals of neutral atoms in basic state (calculated via atom ionization energy)
Appendix IV. P-parameters of some atoms calculated via electron bond energy according to Fischer
Appendix V. Calculations of P0-parameters of some atoms using electron bond energy by ESCA
Appendix VI. Calculations of errors when estimating solubility of components using Parameter method
Appendix VII. Methods of experiments conducted for determining the solubility boundaries of complex system components
Appendix VIII. Analog comparisons of Lagrangian and Hamilton functions with spatial-energy parameter