The bulky molecules 1,3,5-tri-t-butylbenzene and 2,4,6-tribromo-1,3,5-triethylbenzene have been sorbed at 180°C into zeolite NaX and the resulting inclusion compounds characterised. The molecules have minimum diameters of approximately 0.90 nm and 0.95 nm respectively; this significantly exceeds the
✦ LIBER ✦
Sorption states of isoelectronic linear molecules in zeolites
✍ Scribed by H. Böse; H. Förster
- Publisher
- Elsevier Science
- Year
- 1990
- Tongue
- English
- Weight
- 307 KB
- Volume
- 218
- Category
- Article
- ISSN
- 0022-2860
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## Abstract Sorption and desorption in zeolites (molecular sieves) have to be considered as complex processes, involving simultaneous diffusion in zeolite crystals, mass transfer in the intercrystalline void of a pellet, and heat transfer between the zeolitic sorbent and its surroundings. The kinet