Sorption of target anions by ligand exchange
✍ Scribed by Y. Çengeloğlu; B. Mercimek; H. Kara; M. Ersöz
- Publisher
- John Wiley and Sons
- Year
- 1998
- Tongue
- English
- Weight
- 122 KB
- Volume
- 69
- Category
- Article
- ISSN
- 0021-8995
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✦ Synopsis
The sorption of anionic ligands such as I 0 , Br 0 , and SCN 0 onto diaminoethyl-sporopollenin (DAE-sporopollenin) was investigated in both column and batch experiments at room temperature. The isotherm binding constants suggest that the resin is most efficient at the binding of I 0 compared with Br 0 or SCN 0 . The general ligand sorption affinity series observed was I 0 ú Br 0 ú SCN 0 . This ligand sorption could be described by considering the hydration of ions in the exchanger. The sorption behavior of the ligand exchanger and the possibilities of selectively removing and recovering ligands are discussed on the basis of their chemical and complexing properties.
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Sorption characteristics of eight mono-carboxylic acids by an anion-exchange membrane were studied. The experiments were carried out as batch determinations of the equilibrated concentrations of chloride and carboxylic acid in the membrane and the solution. The sorption of a carboxylic acid by the i
Bcschreibung eincr Untcrsuchung iiber die Faktorcn, welchc die chromatographischc Trennung von Osy-slurcn mit I?\nioncnaustauschcrn in der 13orat-Form bccinflusscn. Gcringcrc I3oratkonzentration im Eluierungsmittcl crgibt eincn h6hcrcn Trcnnungsfaktor. I Unc Btudc a &td effcctuGc sur lcs divers fact
A comparative study of kinetic models for ligand exchange of I 0 r Cl 0 and Br 0 r Cl 0 as ligands as a function of pH and concentration using diaminoethylsporopollenin (DAE-sporopollenin) resin were investigated during the ligand-exchange reaction of the liquid phase. A batch technique was employed