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Sorption of target anions by ligand exchange

✍ Scribed by Y. Çengeloğlu; B. Mercimek; H. Kara; M. Ersöz


Publisher
John Wiley and Sons
Year
1998
Tongue
English
Weight
122 KB
Volume
69
Category
Article
ISSN
0021-8995

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✦ Synopsis


The sorption of anionic ligands such as I 0 , Br 0 , and SCN 0 onto diaminoethyl-sporopollenin (DAE-sporopollenin) was investigated in both column and batch experiments at room temperature. The isotherm binding constants suggest that the resin is most efficient at the binding of I 0 compared with Br 0 or SCN 0 . The general ligand sorption affinity series observed was I 0 ú Br 0 ú SCN 0 . This ligand sorption could be described by considering the hydration of ions in the exchanger. The sorption behavior of the ligand exchanger and the possibilities of selectively removing and recovering ligands are discussed on the basis of their chemical and complexing properties.


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