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Sorbitol transformation in aqueous medium: Influence of metal/acid balance on reaction selectivity

โœ Scribed by L. Vilcocq; A. Cabiac; C. Especel; S. Lacombe; D. Duprez

Book ID
116344485
Publisher
Elsevier Science
Year
2012
Tongue
English
Weight
534 KB
Volume
189
Category
Article
ISSN
0920-5861

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The regioselectivity of the reaction of ethyl acetoacetate on allylic carbonate in the presence of a catalyst prepared from Pd(OAc), and P(C,H,-m-SO,Na), (or tppts) is not affected by the ratio Pd(OAc),/tppts, the nature of the nitrile, the relative amounts of water and nitrile or the temperature of