Some unusual crystallization phenomena in frozen aqueous solutions
β Scribed by S.L. Ruby; A. Bernabei; B.J. Zabransky
- Publisher
- Elsevier Science
- Year
- 1972
- Tongue
- English
- Weight
- 415 KB
- Volume
- 13
- Category
- Article
- ISSN
- 0009-2614
No coin nor oath required. For personal study only.
β¦ Synopsis
N%cn a 30 weight p¢ ferrous chloride solution is quick cooied to 78"K, it forms-a transparent glasr When this is slowly.w&ned; both differential thermal analysis and Xlijssbauer measurements distinguish four temperatures, wbidh correspond to (1) melting from glass to undercooled liquid, (2) crystallization of salt-free ice. (3) crystalliza-'r tion of FeCl~;9H~O, and (4) melting of both crystals. Our recent differential-thermal-analysis measurements show that the third temperattiIe increases bjr 22Β°K.as the fraction of DzO in the water increases from zero to 100 percent, &h&he other three remain nearly constant. The cause of the large isotspe effect is not known. .' These measurements on fro&n aqueous solutions of ferrous &loride by use of differential thermal analysis are. a supplement to our larger study of the glassy stat& of matter.by.us+ of the-h4fassbauer eff&t. This DTA technique, which is well adapted for studying phke changes in solids, consists basically in me%.uring the tetip,erature differences between a sample arid a ,matched reference cell when bsth are placed in an oven that is warmed at a steady rate. Melting and freezing L endo-and exothermic processes -are seen ',' '.
π SIMILAR VOLUMES
Emulsification of lauric acid in an aqueous ethanol solution including lauric acid solute has been observed during cooling before crystallization of lauric acid occurs. The nature of two different solubility curves was explained for the system of lauric acid and aqueous ethanol solution. The mutual
Excitation spectra of anthracene were recorded in the temperature range 80 -270 K in various frozen aqueous solutions containing the surfactants cetyltrimethylammonium halide CTAX (X = F, Cl, Br, I) or alkali dodecylsulphate MDS (M = Na, Cs). Fluorescence quantum yields (relative values) were obtain