✦ LIBER ✦

Some studies on the electrochemical oxidation of N-[1-Methyl-2:3-Dihydroxy-cyclopenten(2)-ylidene(4)] piperidinium betaine(I)

✍ Scribed by T.A. Joslin; B.D. Baigrie

Publisher: Elsevier Science
Year: 1981
Tongue: English
Weight: 387 KB
Volume: 26
Category: Article
ISSN: 0013-4686
DOI: 10.1016/0013-4686(81)85050-5

No coin nor oath required. For personal study only.

✦ Synopsis

Abatrnct

-Theoxidation of N-[l-Methyl-2:3dihydroxy-cyclopenten(2)-ylidene(4)]

pip+dinium Maine(k) was investigated using electrochemical methods. The betaine was observed to be oxidiaai in an irreversible two-electron process to give fragmentation products. The major product resulted from the attack of piperidine on the enamine intermediate which is obtained through the two-electron oxidation of (I).