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Some reactions of the octahalodirhenate(III) ions. IV. Reactions with sodium thiocyanate and the preparation of isothiocyanate complexes of rhenium(III) and rhenium(IV)

✍ Scribed by Cotton, F. Albert; Robinson, William R.; Walton, Richard A.; Whyman, Robin


Book ID
125995847
Publisher
American Chemical Society
Year
1967
Tongue
English
Weight
809 KB
Volume
6
Category
Article
ISSN
0020-1669

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The reaction of the octachlorodirhenate(
✍ F.Albert Cotton; Phillip E. Fanwick; Patrick A. McArdle πŸ“‚ Article πŸ“… 1979 πŸ› Elsevier Science 🌐 English βš– 370 KB

## Methyl isocyanide reacts rapidly with (NBu"&-RezQs in ethanol at 25 "C to give a green product, shown by X-my ctystallogmphic study to be (NBu"J [ReCYs(CNCHJ]. The [ReCls(CNCHJ-ion is essentially octahedml, with all cis Re-Cl distances in the range 2.316( 7) A to 2.336(7) A and the trans Re-Cl di