𝔖 Bobbio Scriptorium
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Some propositions related to a dilation theorem of W. Benz

✍ Scribed by John A. Baker


Publisher
Springer
Year
1994
Tongue
English
Weight
391 KB
Volume
47
Category
Article
ISSN
0001-9054

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Five 16Ξ±,17Ξ±-oxido-steroids were subjected to acids, bases and lithium hydroperoxide. Acids caused Wagner-Meerwein-type rearrangement irrespective of the side-chain structure. The 16Ξ±,17Ξ±-epoxides proved resistant to bases unless a C( 22)\_O group was present; in the case of 22-esters or 22-ketones