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Some properties of the ( F o – F c )-synthesis

✍ Scribed by Cochran, W. (author)


Book ID
114515705
Publisher
International Union of Crystallography (IUCr)
Year
1951
Tongue
English
Weight
423 KB
Volume
4
Category
Article
ISSN
0365-110X

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Free difluoroethyne FCCF: isolation,
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Oifluoroethyne F-CEC-F (1) is the last of the dihaloethyne molecules which, in spite of the continuing chemical and theoretical interest, could hitherto not be properly characterized. We have now synthesized and isolated pure 1 on a 50 mg scale by vacuum pyrolysis of perfluoro-1,2,3-triazene and cha