Some principles of the thermal polymerization of phenylacetylene and 2-methyl-5-ethynylpyridine
β Scribed by G. N. Bantsyrev; I. M. Scherbakova; M. I. Cherkashin; I. D. Kalikhman; A. N. Chigir'; A. A. Berlin
- Book ID
- 112456837
- Publisher
- Springer
- Year
- 1970
- Tongue
- English
- Weight
- 553 KB
- Volume
- 19
- Category
- Article
- ISSN
- 1573-9171
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The emulsion polymerization of 2-methyl-5-vinylpyridine (MVP) initiated by potassium persulphate in the presence of two anionic emulsifiers, sodium lauryl sulphate (NaLS) and sodium oleate, was investigated. The effects of persulphatΒ’ and emulsifier concentration on the rate of polymerization are no
## Abstract The inhibiting activity of poly (2βmethylβ5βethynylpyridine) (PEP) has been studied in the cumene oxidation reaction initiated by azobisisobutyronitrile at 55β65Β°C. According to the kinetic data the reaction between RO~2~ radical and PEP is irreversible. About 12% of the most active mac