✦ LIBER ✦

Some polymers and copolymers of vinyldiphenylphosphine

✍ Scribed by Paisley, David M. ;Marvel, C. S.

Publisher: John Wiley and Sons
Year: 1962
Weight: 286 KB
Volume: 56
Category: Article
ISSN: 0022-3832
DOI: 10.1002/pol.1962.1205616424

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✦ Synopsis

Abstract

Vinyldiphenylphosphine has been homopolymerized with aluminumisobutyl/titanium tetrachloride catalysts and with boron fluoride etherate to give low molecular weight oily products. The same monomer has been copolymerized with ethylene and butadiene using Ziegler‐type catalysts and with styrene using azobisisobutyronitrile as the initiator. None of the polymers has a high molecular weight, as indicated by inherent viscosity determinations.

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