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Some Organolithium Compounds Containing Silicon

โœ Scribed by Gilman, Henry; Gorsich, Richard D.


Book ID
127138667
Publisher
American Chemical Society
Year
1962
Tongue
English
Weight
246 KB
Volume
27
Category
Article
ISSN
0022-3263

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Chemoselective acylation of some oxidofu
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Once oxidofunctionalised organolithium compounds 1 (easily prepared by reductive ring opening of isochroman and phthalan by DTBB-catalysed lithiation) were transmetallated with ZnBr 2 /CuCNโ€ข2LiCl and reacted successively with a carboxylic acid anhydride and an acyl chloride in THF at 08C, the corres