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Some novel prospective polymer electrolytes containing potassium ion for electrochromic devices, with preliminary tests on Prussian blue/KxWO3 electrochromic windows

✍ Scribed by Jean-Guy Béraud; Daniel Deroo


Publisher
Elsevier Science
Year
1993
Tongue
English
Weight
890 KB
Volume
31
Category
Article
ISSN
0927-0248

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✦ Synopsis


Different anhydrous potassium ion conducting polymer electrolytes have been studied: (POE)nKTFSI (trifluorosulfonimide), plasticized (POE),KTFSI, (PEM),KTFSI and (POEacetal),KTFSl. DSC and conductivity measurements have been used to characterize these electrolytes. Several solutions to avoid crystallization have been examined. The best conductivity has been obtained with (POE-acetal)nKTFSI. This electrolyte exhibits good transmission in the VIS-IR region. The time response of cells using these electrolytes and Prussian blue and KxWO 3 as electrodes has been measured and compared. The influence of H20 on cycling is also presented and discussed.