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Some mechanism aspects of epoxide polymerization. Stereochemical structure of the crystalline polymers from the 2,3-epoxybutanes

โœ Scribed by Vandenberg, E. J.


Book ID
104533176
Publisher
Wiley (John Wiley & Sons)
Year
1964
Tongue
English
Weight
233 KB
Volume
2
Category
Article
ISSN
0449-2986

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Effect of substituents at position 4 on
โœ L. Porri; M.C. Gallazzi ๐Ÿ“‚ Article ๐Ÿ“… 1966 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 551 KB

Abstraet--4.Methyl-l,3-pentadiene has been polymerized by heterogeneous catalysts from AI(C2Hs) 3 and either TIC14, TIC13 or VCI3, to give polymers having almost exclusively 1,2 units, and showing crystallinity attributable to 1,2 isotactic sequences. Homogeneous systems from AI(C2Hs)3 and either a