Some first row transition metal complexes of nicotinamide and nicotinic acid
β Scribed by J. R. Allan; N. D. Baird; A. L. Kassyk
- Publisher
- Springer Netherlands
- Year
- 1979
- Tongue
- English
- Weight
- 572 KB
- Volume
- 16
- Category
- Article
- ISSN
- 0022-5215
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π SIMILAR VOLUMES
There have been comparatively few studies made on the complex formation between phenolate anions and metal ions. Much of the interest has been focused on the colored complex of iron(III) phenolate and formation constants of this complex were recorded (1). We previously reported the equilibrium data
## Abstract Lithiated 4βmethylβ2β[(trimethylsilyl)amino]pyridine (Ap^TMS^H) undergoes a salt metathesis reaction with [ScCl~3~(thf)~3~] and FeCl~3~, at low temperature in thf, to yield the homoleptic complexes [Sc(Ap^TMS^)~3~] (1) and [Fe(Ap^TMS^)~3~] (2). An analogous reaction with MnCl~2~, CoCl~2