## Reactants and reaction intermediates of significant volatility will distribute themselves between the liquid and vapor phases to a degree determined by relative flow rates, liquid holdup and other variables. This in turn can affect conversion and selectivity. The effects in the catalytic hydrod
Some effects of vapor-liquid equilibria on performance of a trickle-bed reactor
β Scribed by Vito LaVopa; Charles N. Satterfield
- Publisher
- Elsevier Science
- Year
- 1988
- Tongue
- English
- Weight
- 563 KB
- Volume
- 43
- Category
- Article
- ISSN
- 0009-2509
No coin nor oath required. For personal study only.
β¦ Synopsis
The distribution of reactants and inert liquid between the vapor and liquid phase in a trickle bed reactor used for hydrotreating is affected by H /feed ratio, relative volatilities and temperature. The consequences of altering these varia 3 les are not always immediately obvious. Studies are reported here for two model reactions, the hydrodeoxygenation of dibenzofuran (DBF) (b-p. 285'C) and the hydrogenation of n-butylbenzene (n-BB)(b.p. 183OC) dissolved in either n-hexadecane (b.p. 287OC) or in squalane (b.p. 35OOC). Experimental results, obtained at low conversions, are compared with theoretical predictions.
π SIMILAR VOLUMES
The effect of the addition of an inert liquid into a gas-phase reaction occurring on a solid catalyst was studied using the isomerization of cyclopropane to propylene on a silica-alumina catalyst as the model reaction and one of three hydrocarbon solvents as the liquid. With a nonodsorbing liquid th
## Abstract Liquid holdup and mass transfer rates were measured in a 2.58βcm I.D. tube, packed with glass beads and granular CuO Β· ZnO catalyst or Ξ²βnaphthol particles, and operated as a trickle bed. Gasβtoβliquid (water) transport coefficients were determined from absorption and desorption experim