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SOME EFFECTS OF ORBITAL CONSTRAINT IN TRIS(DIALKYLAMINO)PHOSPHINES

โœ Scribed by Kroshefsky, R. D.; Verkade, J. G.

Book ID
127325671
Publisher
Informa UK (Taylor & Francis)
Year
1979
Weight
433 KB
Volume
6
Category
Article
ISSN
0308-664X

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๐Ÿ“œ SIMILAR VOLUMES

Orbital control in the reductive cleavag
Orbital control in the reductive cleavage of tris(methoxyphenyl)phosphines
โœ Peter H. M. Budzelaar; Johannes A. van Doom; Nico Meijboom ๐Ÿ“‚ Article ๐Ÿ“… 2010 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 218 KB

## Abstract The character of the LUMO of (methoxyphenyl)phosphines determines the reductive cleavage of the Cโ€P bond; a high LUMO energy prevents reduction whereas a small coefficient at the Cโ€P carbon atom leads to a poor cleavage.