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Some Consequences of the Application of Incorrect Gas/Solid Adsorption Isotherm Equations

✍ Scribed by József Tóth

Publisher
Elsevier Science
Year
1997
Tongue
English
Weight
209 KB
Volume
185
Category
Article
ISSN
0021-9797

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✦ Synopsis

the good mathematical applicability, the forms of the two mentioned equations-from a thermodynamic standpoint-are incorrect. As a consequence, the correct specific surface areas of the where U is the coverage and the function c(U) has an adsorbents cannot be calculated. The To ´th equation can be transimplicit form defined as formed to a correct relationship and from this modified form correct values of the specific surface areas and isosteric heats of adsorption can be calculated. This correct form does not violate the c(U) Å (U/p)(dp/dU), [2] old principle of the dynamic equilibrium of physical adsorption.

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