Some characterization of 1-(2-aminoethyl)-piperazine copper(II) chloride, a five coordinate complex
β Scribed by Ronald L. Dotson
- Publisher
- Elsevier Science
- Year
- 1974
- Weight
- 159 KB
- Volume
- 10
- Category
- Article
- ISSN
- 0020-1650
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π SIMILAR VOLUMES
Complexes of 4-(2-aminoethyl) pyridine, p-phenetidine and N,N'-dimethylethanolamine with the chlorides of cobalt(II), nickel(II) and copper(II) have been prepared. The stereochemistry for each of the complexes has been obtained from spectral and magnetic data. The decompositions of the complexes hav
Addition of two equivalents of benzyl bromide to [N,N'-bis(2-mercaptoethy1)-1,5-diazacyclooctane]nickel(II) (Ni-1) produced the green dibenzyl dithioether complex [Ni-l-BzlzBrz] structurally characterized by X-ray crystallography as a sixcoordinate octahedral complex in a monoclinic crystal system a
The crystal structure of a copper(II) complex of 2acetylpyridine 3-piperidylthiosemicarbazone, [Cu(Acpip) 2 ], indicates a tridentate, monoanionic ligand (i. e., pyridine nitrogen, imine nitrogen and thiolato sulfur atoms) and a bidentate, monanionic ligand (i. e., imine nitrogen and thiolato sulfur
## Abstract As a probe of the dinucleating ability of the known but little studied bisβbidentate ligand 3,5βdi(2βpyridyl)β4β(1__H__βpyrrolβ1βyl)β4__H__β1,2,4βtriazole (pldpt) its reactivity towards MX~2~Β·6H~2~O (M = Co^II^, Ni^II^ and Zn^II^; X = ClO~4~^β^ and BF~4~^β^) as well as Cu(ClO~4~)~2~Β·6H~