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Some aspects of the enthalpy of dilution of biological polyelectrolytes

✍ Scribed by J. C. Benegas; A. Di Blas; S. Paoletti; A. Cesàro


Publisher
Springer Netherlands
Year
1992
Tongue
English
Weight
385 KB
Volume
38
Category
Article
ISSN
0022-5215

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A theory proposed by the author as representative of the flow of a general suspension contains three "interaction forces", f, S and N. For a "quasiconcentrated suspension" and for a "dilute suspension", N and S, N are omitted, respectively. For the latter special case, we treat diffusion of a fluid

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A new method is proposed for the determination of the enthalpy and entropy changes of nonionic origin upon conformational transition of linear biopolyelectrolytes in solution. For all transition midpoints, defined by given temperature and ionic strength, the total free energy change of the system is