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Some aspects of the DNA hypochromic effect theory

✍ Scribed by S. N. Volkov


Publisher
John Wiley and Sons
Year
1979
Tongue
English
Weight
646 KB
Volume
16
Category
Article
ISSN
0020-7608

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✦ Synopsis


Abstract

The expressions for the polymer absorption band hypochromism and oscillator strength are studied in frames of the first‐order perturbation theory. The physically justified approximations for a polymer hypochromism calculation are indicated. The uniform interpretation of the effect origin is given independently on the approximation used. In frames of the perturbation theory the DNA hypochromism formula is obtained, from which the known experimental dependences of hypochromism on chain length and polymer helicity degree follows directly. The analytic expression of the DNA hypochromism dependence on AT pairs content is obtained. It is established that in most cases for natural DNA the nucleotide sequence does not influence in practice the value of the hypochromic effect.


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