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Some additional aspects of versatile starting compounds for cationic organoiron complexes: molecular structure of the aqua complex [(η5-C5Me4Et)Fe(CO)2(OH2)]BF4 and solution behavior of the THF complex [(η5C5R5)Fe(CO)2(THF)]BF4

✍ Scribed by Munetaka Akita; Masako Terada; Masako Tanaka; Yoshihiko Morooka


Publisher
Elsevier Science
Year
1996
Tongue
English
Weight
807 KB
Volume
510
Category
Article
ISSN
0022-328X

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Cleavage of the Fe–Fe Bond of (Me2SiSiMe
✍ Hud-Lin Sun; Zhen-Sheng Zhang; Xiu-Zhong Zhou 📂 Article 📅 2010 🏛 John Wiley and Sons 🌐 English ⚖ 327 KB 👁 1 views

## Abstract The reaction of the title cyclic complex (1) with sodium amalgam in THF resulted in the expected cleavage of the Fe—Fe bond to afford bis‐sodium salt (Me~2~SiSiMe~2~) [η^5^‐C~5~H~4~Fe (CO)~2~Na]~2~ (4). The latter was not isolated and was used directly to react with MeI, PhCH~2~Cl, CH~3