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Some Acetate Migration and Participation Reactions in Steroids 1

✍ Scribed by SCHULTZ, ROBERT G.


Book ID
126434709
Publisher
American Chemical Society
Year
1959
Tongue
English
Weight
482 KB
Volume
24
Category
Article
ISSN
0022-3263

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In two earlier publications2 we discussed activation volumes of a number of solvolysis reactions considered by many chemists to proceed at enhanced rates because of neighboring group participation. This activation parameter, the value of which is typically3 of the order of -15 --20 cm3/mole for sol