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Solvothermal synthesis, structural characterization and properties of two new layered lanthanide sulfates

✍ Scribed by Lü, Yun; Zhang, Deng; Xu, Yan

Book ID
126227216
Publisher
Elsevier Science
Year
2013
Tongue
English
Weight
617 KB
Volume
29
Category
Article
ISSN
1005-9040

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Two new bimetallic sulfides, (Haep) 2 ÁGa 2 Sb 2 S 7 (1) and Mn 2 (phen)Sb 2 S 5 (2), have been synthesized under solvothermal conditions, where aep = 1-(2-aminoethyl)piperazine and phen = 1,10-phenanthroline. The structure of 1 consists of GaS 4 tetrahedra and SbS 3 trigonal pyramids and has a laye