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Solvolytic Ring-opening of Alkoxychlorofluorocyclopropanes: A Ready Access to Fluorinated α,β-Unsaturated Aldehydes and Ketones

✍ Scribed by Yvonne Bessière; Dang Ngoc-Huê Savary; Manfred Schlosser

Publisher: John Wiley and Sons
Year: 1977
Tongue: German
Weight: 530 KB
Volume: 60
Category: Article
ISSN: 0018-019X
DOI: 10.1002/hlca.19770600528

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✦ Synopsis

Abstract

Alkoxychlorofluorocyclopropanes are easily prepared by chlorofluorocarbene addition to en‐ethers in a two‐phase system and converted by simple heating in an aqueous solvent mixture to 2‐fluoro‐2‐alkenals which can be reduced to the corresponding alcohols.

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