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Solvolytic extraction of coal through acylation and amidomethylation

✍ Scribed by Durlubh K. Sharma; Zulfikar B. Mirza; Manoj K. Sarkar

Book ID
103092640
Publisher
Elsevier Science
Year
1983
Tongue
English
Weight
347 KB
Volume
62
Category
Article
ISSN
0016-2361

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✦ Synopsis

Carboxylic acids, acid anhydrides and N-hydroxy methylamides were used to acylate Assam coal under Friede!-Crafts reaction conditions. This reaction resulted in the enhancement of the extractability of coal in benzenmethanol (7:3 vol./vol.) and quinoline after acylation with carboxylic acids and acid anhydrides.Theeffect of catalyst (AICI,) concentration on reaction wasalso investigated. 1.1. spectra of reaction products indicated the introduction of acyl groups in the coal structure. Phthalimidomethylation could render about 5% coal extractable in quinoline.

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