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Solvolysis of p,p'-dichlorobenzhydryl chloride in ethanol-2,2,2-trifluoroethanol mixtures

โœ Scribed by Rappoport, Zvi; Ben-Yacov, Hadassah; Kaspi, Joseph

Book ID
126145727
Publisher
American Chemical Society
Year
1978
Tongue
English
Weight
914 KB
Volume
43
Category
Article
ISSN
0022-3263

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โœ Walter S. Trahanovsky; Michael P. Doyle ๐Ÿ“‚ Article ๐Ÿ“… 1968 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 205 KB

Solvolysis of 5-hexenyl arenesulfonates can be viewed as two competing nucleophilic reactions: a) external nucleophilic attack by the hydroxylic solvent to give 5-hexenyl products and b) internal nucleophilic attack by the olefin to give cyclic products (1). It is possible that the ratio of open to