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Solvolysis of phosphoric acid esters. Hydrolysis of methyl, ethyl, isopropyl, and tert-butyl dihydrogen phosphates

✍ Scribed by Kugel, Lea; Halmann, Mordechai


Book ID
120382870
Publisher
American Chemical Society
Year
1967
Tongue
English
Weight
784 KB
Volume
32
Category
Article
ISSN
0022-3263

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Gas-phase elimination kinetics of ethyl,
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The elimination kinetics of ethyl, isopropyl and tert-butyl N,N-diethylcarbamates were investigated in a static reaction vessel over the temperature range 220-400 Β°C and pressure range 17-160 Torr. These reactions are homogeneous, unimolecular and follow a first-order rate law. The temperature depen