Solvolysis of p-2-norbornyl-tert-cumyl chlorides. .sigma.+Constants for p-exo- and -endo-Norbornyl and the question of an unusual polarizability of the .sigma.-bonds in the 2-norbornyl group
β Scribed by Brown, Herbert C.; Gnedin, Boris G.; Takeuchi, Kenichi; Peters, Edward N.
- Book ID
- 127286256
- Publisher
- American Chemical Society
- Year
- 1975
- Tongue
- English
- Weight
- 461 KB
- Volume
- 97
- Category
- Article
- ISSN
- 0002-7863
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π SIMILAR VOLUMES
The large difference between the reaction constants p, for the solvolysis of the 6-exo-and 7-anti-substituted norbornyl tosylates 3 and 1, respectively, is further proof for the hypothesis that 2-norbornyl cations are anisotropic with regard to the transmission of polar effects and that through spac
## Abstract The solvolysis rates and products of the 6β__exo__βsubstituted 2β__exo__β **1a**β**1u**, and 2β__endo__βnorbornyl __p__βtoluenesulfonates **2a**β**2u**, have been determined. In general, the rate constants for **1** and **2** (log __k__) correlate well with the inductive constants Ο of