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Solvolysis mechanisms. Kinetic solvent isotope effects for alkyl tosylates in acetic acid and acetic acid-d

โœ Scribed by Huang, Theresa S. C. C.; Thornton, Edward R.


Book ID
126318039
Publisher
American Chemical Society
Year
1976
Tongue
English
Weight
521 KB
Volume
98
Category
Article
ISSN
0002-7863

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Kinetic solvent isotope effects (KSIE) were measured for the hydrolyses of acetals of benzaldehydes in aqueous solutions covering the pH (pD) range of 1-6. For p-methoxybenzaldehyde diethyl acetal, kD+/kH+ = 1.8-3.1, depending on the procedure used to calculate the KSIE and on the pH (pD) range used