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Solvolysis mechanism of tertiary α-silyl bromides

✍ Scribed by Frank K. Cartledge; John P. Jones


Book ID
108351253
Publisher
Elsevier Science
Year
1974
Tongue
English
Weight
711 KB
Volume
67
Category
Article
ISSN
0022-328X

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📜 SIMILAR VOLUMES


γ-Silyl-stabilized tertiary ions? Solvol
✍ Leon J. Tilley; V. J. Shiner Jr 📂 Article 📅 1999 🏛 John Wiley and Sons 🌐 English ⚖ 143 KB 👁 1 views

Rate constant, isotope-effect, and product studies of the solvolysis of 4-(trimethylsilyl)-2-chloro-2methylbutane, 11, and its carbon analog, 2-chloro-2,5,5-trimethylhexane, 10, in aqueous ethanol and aqueous 2,2,2trifluoroethanol (TFE) indicate very little participation of the g-silyl substituent.